筒鞘蛇菰乙酸乙酯部位的化学成分研究(3)
化合物2:淡黄色无定型粉末;盐酸-镁粉反应阳性;UVλmax:278.9 nm;ESI-MS m/z 311.2[M+Na]+;分子式:C15H12O6,分子量:288。1H-NMR(DMSO-d6,600 MHz) δH:6.87(1H,s,H-4′ ),6.74(2H,s,H-2′ ,6′ ),5.88(2H,s,H-6,8),5.38(1H,dd,J=12.6,3.0 Hz,H-2),3.19(1H,dd,J=17.4,12.6 Hz,H-3b),2.67(1H,dd,J=17.4,3.0 Hz,H-3a);13C-NMR(DMSO-d6,150 MHz)δC:196.4(C-4),166.7(C-7),163.5(C-9),162.9(C-5),145.7(C-5′ ),145.2(C-3′ ),129.4(C-1′ ),118.0(C-4′ ),115.3(C-6′ ),114.4(C-2′ ) ......
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