普洱茶中黄酮类化学成分研究(4)
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Chemical constitutes of flavones from Pu,erh tea
ZHANG Liang, TU Peng,fei*
(State Key Laboratory of Natural and Biomimetic Drugs, Peking University School of
Pharmaceutical Sciences, Beijing 100191, China)
[Abstract]The chemical constituents in the Pu,erh tea were isolated by various column chromatographic methods, and their structures were identified by spectral data and physic,chemical analysis. As a result, eleven flavonoids were isolated and identified as kaempferol (1), quercetin (2), kaempferol,3-O,β,D-glucopyranoside (3), kaempferol,3-O,β,D-rutinoside (4), apigenin,6-C,α,L-arabinopyranosyl,8-C,β,D-glucopyranoside (5), vitexin,4″-O,β,D-glucopyranoside (6), kaempferol,3-O,[α,L-rhamnopyranosyl,(1→3)-α,L-rhamnopyranosyl,(1→6)-β,D-glucopyranoside] (7), quercetin3-O,β,D-glucopyranoside (8), rutin (9), quercetin,3-O,α,L-rhamnopyranoside (10), and myricetin,3-O,β,D-glucopyranoside (11). Compounds 5,7, 10 and 11 were isolated from Pu,erh tea for the first time.
[Key words]Camellia sinensis var. assamica; flavones; chemical constituents
doi:10.4268/cjcmm20131020, http://www.100md.com(张梁 屠鹏飞)
Chemical constitutes of flavones from Pu,erh tea
ZHANG Liang, TU Peng,fei*
(State Key Laboratory of Natural and Biomimetic Drugs, Peking University School of
Pharmaceutical Sciences, Beijing 100191, China)
[Abstract]The chemical constituents in the Pu,erh tea were isolated by various column chromatographic methods, and their structures were identified by spectral data and physic,chemical analysis. As a result, eleven flavonoids were isolated and identified as kaempferol (1), quercetin (2), kaempferol,3-O,β,D-glucopyranoside (3), kaempferol,3-O,β,D-rutinoside (4), apigenin,6-C,α,L-arabinopyranosyl,8-C,β,D-glucopyranoside (5), vitexin,4″-O,β,D-glucopyranoside (6), kaempferol,3-O,[α,L-rhamnopyranosyl,(1→3)-α,L-rhamnopyranosyl,(1→6)-β,D-glucopyranoside] (7), quercetin3-O,β,D-glucopyranoside (8), rutin (9), quercetin,3-O,α,L-rhamnopyranoside (10), and myricetin,3-O,β,D-glucopyranoside (11). Compounds 5,7, 10 and 11 were isolated from Pu,erh tea for the first time.
[Key words]Camellia sinensis var. assamica; flavones; chemical constituents
doi:10.4268/cjcmm20131020, http://www.100md.com(张梁 屠鹏飞)