红茴香甲醇部位化学成分研究(3)
[11] Nobuko S，Masato K，Atsushi S， et al.Berchemolide，a novel dimeric vanillic acid glucoside from Berchemia racemosa[J].Chem Pharm Bull，1992，40(4)：853.
[12] Kirsten B，Tadao K，Hideki A，et al.Structure and biosynthesis of anthocyanins in flowers of Campanula [J].Phytochemistry，1993，33(1)：212.
Chemical constituents of methanol portion of Illicium henryi
HE Lan-yun， HUANG Hai-jiang
(Dongguan National Medicine Group Co.， Ltd.， of Guangdong Province， Dongguan 441900， China)
[Abstract] To study the chemical constituents of the methanol portion of the stem of Illicium henryi. The methanol portion was isolated and purified by HP-20， ODS， Sephadex LH-20 column chromatography， and preparative HPLC. Their structures were elucidated by MS and spectral data(1H， 13C-NMR). Five compounds were isolated from the methanol portion and identified as benzyloxy-1-O-β-D-glucopyranoside (1)， 4-hydroxy-phenethyl alcohol-O-β-D-glucopyranoside(2)， 3-methoxyl-4-hydroxyl-phenpropanol-O-β-D-glucopyranoside (3)， 3-methoxyl-4-O-β-D-glucopyranosyloxy-benzoic acid methyl ester (4)， and 4-O-β-D-glucopyranosyloxy-benzoic acid methyl ester(5). All compounds were isolated from this plant for the first time.
[Key words] Illicium； Illicium henryi； methanol portion； chemical constituents
doi：10.4268/cjcmm20140520
[责任编辑 孔晶晶], 百拇医药(贺兰云 黄海疆)
[12] Kirsten B，Tadao K，Hideki A，et al.Structure and biosynthesis of anthocyanins in flowers of Campanula [J].Phytochemistry，1993，33(1)：212.
Chemical constituents of methanol portion of Illicium henryi
HE Lan-yun， HUANG Hai-jiang
(Dongguan National Medicine Group Co.， Ltd.， of Guangdong Province， Dongguan 441900， China)
[Abstract] To study the chemical constituents of the methanol portion of the stem of Illicium henryi. The methanol portion was isolated and purified by HP-20， ODS， Sephadex LH-20 column chromatography， and preparative HPLC. Their structures were elucidated by MS and spectral data(1H， 13C-NMR). Five compounds were isolated from the methanol portion and identified as benzyloxy-1-O-β-D-glucopyranoside (1)， 4-hydroxy-phenethyl alcohol-O-β-D-glucopyranoside(2)， 3-methoxyl-4-hydroxyl-phenpropanol-O-β-D-glucopyranoside (3)， 3-methoxyl-4-O-β-D-glucopyranosyloxy-benzoic acid methyl ester (4)， and 4-O-β-D-glucopyranosyloxy-benzoic acid methyl ester(5). All compounds were isolated from this plant for the first time.
[Key words] Illicium； Illicium henryi； methanol portion； chemical constituents
doi：10.4268/cjcmm20140520
[责任编辑 孔晶晶], 百拇医药(贺兰云 黄海疆)