猫眼草化学成分研究(5)
化合物11 白色粉末(乙酸乙酯);mp 142~144 ℃;ESI-MS m/z 479[M+Na]+;1H-NMR(CDCl3,600 MHz)δ:4.71(1H,br s,H-31a),4.66(1H,br s,H-31b),3.76(1H,dd,J=13.6,4.3 Hz,H-3),3.74(1H,d,J=10.3 Hz,H-28a),3.52(1H,d,J=10.5 Hz,H-28b),2.23(1H,t,J=6.7 Hz,H-25),1.04(3H,d,J=6.9 Hz,H-26),1.03(3H,d,J=6.9 Hz,H-27),0.96(3H,s,H-18),0.94(3H,s,H-30),0.88(3H,d,J=5.6 Hz,H-21),0.87(3H,s,H-29),0.58(1H,d,J=4.2 Hz,H-19a),0.38(1H,d,J=4.2 Hz,H-19b); 13C-NMR(CDCl3 ......
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